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元阳哈尼梯田湿地土壤铵态氮吸附-解吸特征

Characteristics of Soil Ammonium Nitrogen Adsorption and Desorption in the Hani Terraced Wetland in Yuanyang, Yunnan Province

  • 摘要: 为了探究云南哈尼梯田湿地土壤对铵态氮的吸附-解吸特征,在干季(11月)和湿季(6月)分别采集不同海拔(上部梯田和下部梯田)、不同深度(0~20 cm、>20~40 cm、>40~60 cm和>60~80 cm)的梯田土壤样品,开展铵态氮的吸附-解吸热力学及动力学序批实验,并采用动力学模型和等温热力学模型研究土壤铵态氮的吸附-解吸特征。研究结果表明,哈尼梯田湿地土壤铵态氮的吸附动力学曲线可用准一阶方程拟合;下部梯田土壤铵态氮吸附量在不同月份均比上部梯田高出12%以上,6月不同海拔土壤铵态氮吸附量均比11月高出52%以上,土壤铵态氮吸附量随着土层深度的增加而逐渐增大。哈尼梯田湿地土壤铵态氮吸附热力学曲线均可用Langmuir方程拟合;下部梯田土壤铵态氮最大吸附容量在不同月份均比上部梯田高出19%以上,6月不同海拔铵态氮最大吸附容量均比11月高出67.5%以上,随着土壤深度的增加,土壤铵态氮最大吸附容量逐渐增加。哈尼梯田土壤铵态氮的解吸热力学曲线可用Langmuir方程拟合;下部梯田的铵态氮最大解吸量在不同月份均大于上部梯田;11月不同海拔土壤铵态氮解吸能力均强于6月。哈尼梯田土壤铵态氮临界吸附浓度均小于上覆水,作为铵态氮的“汇”,可以有效地对铵态氮进行吸附,且6月土壤对铵态氮的吸附能力大于11月,下部梯田土壤铵态氮吸附能力大于上部梯田。哈尼梯田湿地对于防止湿地和下部河流的面源污染及富营养化、增强湿地生态系统的生态功能具有重要作用,研究结果可为梯田湿地的可持续发展提供参考。

     

    Abstract: In order to investigate the adsorption and desorption characteristics of ammonium nitrogen by soils in the Hani terraces in Yunnan, soil samples were collected at different altitudes (upper and lower terraces) and depths (0-20, >20-40, >40-60 and >60-80 cm) in the dry season (November) and wet seasons June), respectively. The adsorption and desorption thermodynamics and kinetic sequential batch experiments of ammonium nitrogen were carried out, and the adsorption-desorption critical concentration of soil ammonium nitrogen were calculated by using the kinetic models and isothermal thermodynamic models. The results showed that the kinetic curves of ammonium nitrogen adsorption in the Hani terraces could be fitted by quasi-first-order equations. The ammonium nitrogen adsorption capacities of the lower terraced soils were more than 12% higher than those of the upper terraced soils in different months. The ammonium nitrogen adsorption capacities of soils at different altitudes in June were more than 52% higher than those in November, and the ammonium nitrogen adsorption capacities increased gradually with the soil depths. The thermodynamic curves of ammonium nitrogen adsorption could be fitted by Langmuir's equation. The maximum adsorption capacity of ammonium nitrogen increased gradually with the increase of soil depth, and those in the lower terraces were more than 19% higher than those in the upper terraces in different months. The maximum adsorption capacities of ammonium nitrogen at different altitudes in June were more than 67.5% higher than those in November. The desorption thermodynamic curve of ammonium nitrogen in Hani terraced soil can be fitted using the Langmuir equation. The maximum desorption of ammonium nitrogen in the lower terraced fields is greater than that in the upper terraced fields in different months. The desorption capacity of ammonium nitrogen in soils at different altitudes in November was stronger than that in June. The thermodynamic curves of ammonium nitrogen desorption in the Hani terraced soils could be fitted by the Langmuir equation. The maximum ammonium nitrogen desorption capacity in the lower terrace was greater than that in the upper terrace in different months. The maximum ammonium nitrogen desorption capacity in soils at different elevations in November was greater than that in June. The critical adsorption concentration of ammonium nitrogen in the Hani terrace was lower than that in the overlying water, and as a ‘sink’ for ammonium nitrogen, it could effectively adsorb ammonium nitrogen. Moreover, the adsorption capacity of soils for ammonium nitrogen in June was greater than that in November, and the ammonium nitrogen adsorption capacity in the lower terraced soil was greater than that in the upper terraced soil. The Hani terraced wetlands play an important role in preventing surface source pollution and eutrophication of wetlands and lower rivers, and enhancing the ecological function of wetland ecosystems. The findings can provide references for the sustainable development of terraced wetlands.

     

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